€ 54,00*
SIZE
100 - 200 mesh
Capacity
1 - 1.5 mmol/g
Product number
HR10031-0.5G
HR10031-0.5G
Product information
Useful resin for solid phase Wittig reactions as well as solid phase Staudinger-aza-Wittig reactions. This polymer bound triphenylphosphin has also been used for halogenation reactions as well as a scavenger resin for alkyl halides and palladium.
Other applications are the use as a polymer bound ligand for transition metals in transition metal catalyzed reactions.
Other capacities and particle sizes on request
Literature
L 44 Polymeric Reagents
- Fyles, T. M.; Leznoff, C. C. The use of polymer supports in organic synthesis. V. The preparation of monoacetates of symmetrical diols. Can. J. Chem. 1976, 54 (6), 935-942. doi: 10.1139/v76-135.
- Crosby, G. A.; Weinshenker, N. M.; Uh, H.-S. Polymeric Reagents. III. Synthesis of an Insoluble Polymeric Thioanisole and Its Utilization for the Oxidation of Alcohols. J. Am. Chem. Soc. 1975, 97 (8), 2232-2235. doi: 10.1021/ja00841a039.
- Weinshenker, N. M.; Shen, C.-M. Polymeric Reagents I. Synthesis of an Insoluble Polymeric Carbodiimide. Tetrahedron Lett. 1972, 13 (32), 3281-3284. doi: 10.1016/s0040-4039(01)94023-7.
- Daly, W. H. Influence of Support Structure on Preparation and Utilization of Polymeric Reagents. Makromol. Chem. 1979, 2 (S19791), 3-25. doi: 10.1002/macp.1979.020021979101.
- Overberger, C. G.; Sannes, K. N. Polymere als Reagentien für organische Synthesen. Angew. Chem. Weinheim Bergstr. Ger. 1974, 86 (4), 139-145. doi: 10.1002/ange.19740860402.
- Akelah, A.; Sherrington, D. C. Recent Developments in the Application of Functionalized Polymers in Organic Synthesis. Polymer (Guildf.) 1983, 24 (11), 1369-1386. doi: 10.1016/0032-3861(83)90218-5.
- Atherton, E.; Sheppard, R. C. in Peptides 1974: Proceedings of the Thirteenth European Peptide Symposium (Wolman, Y., Ed.), Kiryat, 'Anavim, Israel, Wiley & Sons, NY (1975), 123.
L 45 Triphenylphosphine Resins
- Bernard, M.; Ford, W. T. Wittig Reagents Bound to Crosslinked Polystyrenes. J. Org. Chem. 1983, 48 (3), 326-332. doi: 10.1021/jo00151a010.
- Hodge, P.; Richardson, G., Conversion of acids -- and alcohols into -- chlorides using a polymer-supported phosphine, Chem. Commun., 1975, 15, 622-623. doi: 10.1039/c39750000622.
- Caputo, R.; Ferreri, C.; Noviello, S.; Palumbo, G. Use of Polymeric Phosphine-Halogen Complexes in the Conversion of Epoxides to Halohydrins. Synthesis (Mass.) 1986, 1986 (06), 499-501. doi: 10.1055/s-1986-31689.
- Caputo, R.; Ferreri, C.; Palumbo, G. A New Ready, High-Yielding, General Procedure for Acetalization of Carbonyl Compounds. Synthesis (Mass.) 1987, 1987 (04), 386-389. doi: 10.1055/s-1987-27955.
- Hughes, I. Application of Polymer-Bound Phosphonium Salts as Traceless Supports for Solid Phase Synthesis. Tetrahedron Lett. 1996, 37 (42), 7595-7598. doi: 10.1016/0040-4039(96)01669-3.
- Fenger, I.; Le Drian, C. Reusable Polymer-Supported Palladium Catalysts: An Alternative to Tetrakis(Triphenylphosphine)Palladium in the Suzuki Cross-Coupling Reaction. Tetrahedron Lett. 1998, 39 (24), 4287-4290. doi: 10.1016/s0040-4039(98)00757-6.