Bromo Polystyrene

Product information

A functional resin for the synthesis of many different aryl based derivatives containing e.g. carboxylic acid, aldehyde, thiol, phosphine or silyl chloride groups. Treatment of this resin with nBuLi generates the intermediate for the mentioned compounds.


Literature

L 27 Bromo Polystyrene Resins

  1. Farrall, M. J.; Frechet, J. M. J. Bromination and Lithiation: Two Important Steps in the Functionalization of Polystyrene Resins. J. Org. Chem. 1976, 41 (24), 3877-3882. doi: 10.1021/jo00886a023.
  2. Fyles, T. M.; Leznoff, C. C. The use of polymer supports in organic synthesis. V. The preparation of monoacetates of symmetrical diols. Can. J. Chem. 1976, 54 (6), 935-942. doi: 10.1139/v76-135.
  3. Randolph, J. T.; McClure, K. F.; Danishefsky, S. J. Major Simplifications in Oligosaccharide Syntheses Arising from a Solid-Phase Based Method: An Application to the Synthesis of the Lewis b Antigen. J. Am. Chem. Soc. 1995, 117 (21), 5712-5719. doi: 10.1021/ja00126a012.
  4. Woolard, F. X.; Paetsch, J.; Ellman, J. A. A Silicon Linker for Direct Loading of Aromatic Compounds to Supports. Traceless Synthesis of Pyridine-Based Tricyclics. J. Org. Chem. 1997, 62 (18), 6102-6103. doi: 10.1021/jo9710745.